Enantioselective Synthesis of P(V)-Stereogenic Phosphacycles by N-Heterocyclic Carbene (NHC)-Catalyzed Desymmetric Annulation
P(V)-stereogenic compounds show diverse biological properties and remain as a focal point in medicinal chemistry and agrochemicals. Traditional approaches to access enantioenriched P(V)-stereogenic molecules largely depend on chromatographic resolution, chiral auxiliaries, and/or the use of optically active starting...