Switching Site Selectivity in Alkoxyamine Hydration: From Lone-Pair Direction to Solvent Network Dominance.
Predicting site selectivity during the earliest stages of solvation in multifunctional organic molecules remains a complex challenge in chemical physics. In this work, we use high-resolution rotational spectroscopy and quantum-chemical calculations to decode the hydration landscape of N,N-diethylacetyloxyamine (DEAcA),...