Author

S. Mishra

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Open access Aug 2026

Substituent-Driven Switch Between Os…O and O…H Interaction and the Emerging Cooperative/Anti-Cooperative Effect in X-Py·OsO4·H2O Ternary Complexes.

In this study, we present a quantum mechanical investigation of Osme-bonded binary and ternary complexes formed between OsO4, substituted pyridines (X-Py; X = NH2, OCH3, OH, CH3, F, Cl, CF3, CN, and NO2), and H2O molecule, highlighting their potential relevance for higher-order cocrystal design without relying predomin...

S. Mishra, Dipankar Sutradhar · ChemPhysChem · 0 citations

Open access Jul 2026

Metal-Centered Noncovalent Interactions: A Comparative Insight into π-Hole- and σ-Hole-Directed Bonds.

This article investigates the π-hole-driven interactions of BeCl2, MgCl2, and HgCl2, as well as the σ-hole-directed interactions of MoOF4 and OsO4 with substituted pyridines. Among the π-hole complexes, the Be…N beryllium bond exhibits the highest binding strength, followed by Mg…N magnesium bond and Hg…N spodium bond,...

S. Mishra, Dipankar Sutradhar · ChemPhysChem · 0 citations