Photocatalyst‐Free Hydrodifluoromethylation of Alkenes via Thiol‐Mediated Photoactivation of Zn(CF 2 H) 2 (DMPU) 2
Herein, we report a photocatalyst‐free hydrodifluoromethylation of alkenes using Zn(CF 2 H) 2 (DMPU) 2 and thiophenols under 390 nm irradiation. The thiophenol serves a dual stoichiometric function, promoting the formation of a photoactive thiol‐modified organozinc species while acting as the terminal hydrogen‐...