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Sep 2026

Structural Fluxionality of Surface Motifs in Positional Isomeric Au14Cd2 Clusters Enables Switchable O–O Bond Activation Pathways

The construction of positional isomers enables tunable control over the physicochemical properties of nanoclusters. However, up to now, the packing model of the core and motif has typically been one-to-one. Herein, we present positional isomeric nanoclusters, Au14Cd2-1 and Au14Cd2-2, which feature an identical Au13 i...

Ye-Sen Tan, Yang-Ping Wang, Qin-Zhen Li et al. · 0 citations
Aug 2026

Gram-Scale Synthesis of N2-Type Ag32 Superatomic Molecule and Its Catalytic Reduction of 4-Nitrophenol.

Cluster assembly serves as an effective approach for tuning cluster properties, ‌where the electronic states arising from fused units play a crucial role in property design, thus attracting attention. In this work, we synthesized a Ag32 cluster via a one-pot method, featuring a Ag22 core formed by fusion of two icosahe...

Li-Jie Feng, Yuxin Hou, Zhiping Liu et al. · 0 citations

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