Ion-Mediated Configuration Regulation and Chiralization in Cu(I) Cluster-Based Metallic Cages.
Emulating the well-controlled conformational switching of biomacromolecules within artificial supramolecular assemblies remains a long-recognized challenge, especially exploring the synergy effects of metal clusters within metalloproteins. Herein, three types of copper cluster-based metallacages (helical Cu8-X, trigona...