Author

T. Hasunuma

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Open access Aug 2026

Engineering a Highly meta -Selective Biphenyl Monooxygenase for the Biosynthesis of High-Value Polymer Precursors

The meta-selective C–H functionalization of aromatic substrates lacking meta-directing electron-withdrawing groups remains challenging. To engineer the regioselective enzymatic conversion of biphenyl (BP) to 3,3′-dihydroxybiphenyl (33DHBP), an industrial precursor to high-performance polymers, substrate positioning w...

C. Vavricka, Takeshi Matsui, Satoshi Yuzawa et al. · ACS Catalysis · 0 citations

Jul 2026

Heterologous polyhydroxyalkanoate synthase expression enables poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) production from fatty acids in Rhodobacter capsulatus.

This study demonstrates PHBH biosynthesis in R. capsulatus and indicates that limited 3HHx-CoA supply rather than polymerization capacity is the primary bottleneck, providing a foundation for further pathway and host optimization toward flexible PHBH production from diverse substrates.

Kako Miura, Takayuki Shimizu, T. Hasunuma et al. · Journal of Bioscience and Bi... · 0 citations

Jul 2026

Metabolic Engineering of Microbial Strains for 1,2,4-Butanetriol Production: Progress and Future Perspectives.

This chapter focuses on research progress in metabolic engineering of BT production, which mainly includes design of BT biosynthetic pathways for expression in bacterial and yeast cell factories, current metabolic engineering and process optimization strategies to optimize BT production, and utilizing lignocellulosic b...

Weibin Wang, Mengrui Tao, Kai Li et al. · Advances in Biochemical Engi... · 0 citations