Enhanced CO2 adsorption and anti-sintering potential of Ni- and Mn-doped CaO(001) for calcium-looping thermochemical energy storage: A first-principles study
Calcium-looping thermochemical energy storage based on the reversible CaCO3/CaO reaction is attractive for concentrating solar power and industrial waste heat recovery, but CaO suffers from sintering and deactivation during repeated high temperature cycling. In this work, density functional theory was used to compare p...