Metal-Oxo Cluster Composition in Metal-Organic Frameworks Controls Solar-Driven CO2 Methanation Pathways.
Although metal-organic frameworks have emerged as versatile and tunable heterogeneous photocatalysts for the hydrogenation of gaseous CO2 to CH4, the role of metal-oxo cluster composition in governing this photocatalytic process remains largely unexplored. Herein, we employ an isostructural series of monometallic MIL-1...