Polymerization-Induced Self-Stabilized High Internal Phase Emulsions via Interfacial Poly(thioacetal) Formation
A polymerization-induced self-stabilization strategy is reported for the fabrication of degradable polymer foams without external surfactants or particulate stabilizers. Specifically, interfacial polycondensation between glyoxal and 1,6-hexanedithiol generates amphiphilic oligomers in situ, which spontaneously adsorb...