Author

Xiao-Guang Duan

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Open access Aug 2026

Side-Chain-Induced Interlayer Slipping in Metalloporphyrin COFs Enables Microenvironment and Spin-State Regulation for Photocatalytic CO2 Reduction.

Photocatalytic CO2 reduction (CO2RR) involves a cascade of intrinsically coupled processes, rendering the independent optimization of catalytic kinetics and thermodynamics challenging. In this study, we introduce a structural regulation strategy via steric-driven interlayer slipping engineering of metalloporphyrin-base...

Jie He, Qingxuan Chen, Min-Xian Zhang et al. · Advances in Materials · 0 citations

Open access Aug 2026

Geometry-Controlled Cooperativity at Binuclear Fe2-N6 Sites Enables Selective FeIV═OGeneration for Durable Fenton-Like Oxidation.

Single atom catalysts (SACs) are emerging as a promising platform for Fenton-like water purification; however, their practical deployment is often constrained by the trade-off between high intrinsic activity and long-term stability. Here, we construct an N-bridged binuclear architecture that pairs isolated Fe-N4 sites...

Shuai Yang, Xinhao Wang, Dong-Dong Chen et al. · Angewandte Chemie · 1 citation

Open access Aug 2026

Engineering N-site isomerism in donor-acceptor covalent organic frameworks for efficient Fenton-like water purification

Covalent organic frameworks (COFs) have emerged as promising candidates for singlet oxygen (1O2) generation via peroxymonosulfate (PMS) activation, yet their structure-property-activity relationships remain poorly understood. Herein, three constitutionally isomeric donor-acceptor COFs (TF-22Bpy, TA-22Bpy and TA-33Bpy)...

Chengming Xiao, Meng-Ting He, Wen-Bo Yang et al. · Nature Communications · 0 citations