Intermediate-Mediated Selectivity in Electrocatalytic Nitrate Reduction for Nitrogen Product Synthesis.
Electrocatalytic nitrate (NO3 -) reduction reaction (eNO3RR) has emerged as a promising strategy for waste NO3 - valorization, offering opportunities for environmental remediation. However, its complex proton-coupled electron transfer processes involve multiple competing pathways, in which the fate of key intermediates...