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Author

Xin Xu

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Oct 2026

Enantioselective Scandium-Catalyzed Benzylic C−H Addition of Tertiary Anilines to Alkenes

Enantioselective C−H addition of aromatic amines to alkenes represents a highly efficient and direct approach for the synthesis of chiral alkylanilines. Herein, we report an enantioselective benzylic C(sp3)−H addition of tertiary anilines to alkenes, enabled by a bulky anilido-oxazoline ligand-supported scandium cata...

Xiang Feng, Jiao Zhang, Qian-Lin Sun et al. · 0 citations
Oct 2026

Regio- and Stereoselective Dimerization of Arylalkynes Mediated by a Transient Zinc Radical

Vinyl radicals are crucial intermediates in synthetic chemistry that readily undergo a range of well-established transformations, such as hydrogen atom transfer and cyclization. Herein, we report a distinct reaction mode in which vinyl radicals, generated from the attack of a transient zinc radical on an alkyne, are...

Qiu-Jie Wang, Shui-Lian Xu, T. Rajeshkumar et al. · 0 citations

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