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Xue-Nian Chen

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Open access Oct 2026

Multifunctional Organoboron Synthesis through Chelation‐Induced Radical Addition Reactions †

Multifunctional organoboron compounds are powerful synthetic platforms, yet the direct and modular assembly of diverse scaffolds from simple precursors remains a significant challenge. Herein, we demonstrate that the inexpensive inorganic base potassium carbonate (K₂CO₃) serves as a unique chelating agent to unlock p...

Da-Long Shen, Ya-Nan Zhang, Jia-Jun Li et al. · 0 citations
Oct 2026

Ultrastable Cycling of Sodium Metal Battery at Rates Exceeding 20 C Achieved with a NaB3H8-SiO2 Composite Solid Electrolyte.

Solid-state sodium metal batteries are promising candidates for grid-scale energy storage due to their inherent safety and low cost. However, the development of solid electrolytes that support high-rate (>20 C) cycling for fast-charging applications remains a major challenge. Herein, we explore how adding SiO2 affects...

An-Qi Zhu, Peng-Tao Qiu, Yan-Qiong Luo et al. · 0 citations
Aug 2026

Synthesis of Carborane-Modified Sugars and Nucleosides via Pd(II)-Catalyzed B-H Bond Activation.

Carborane-modified sugars and nucleosides are promising boron-delivery agents for boron neutron capture therapy (BNCT). Accordingly, a series of carborane-based sugars and nucleosides have been successfully prepared. Nevertheless, current research on such compounds is mainly focused on carbon-site modification of carbo...

Meng Huang, Hao-Tian Zhang, Ge Yuan et al. · 1 citation
Oct 2026

Selective B(4)–H Alkoxylation of o -Carboranes with Alcohols via Heteroleptic Cu(I)-Photocatalyzed 1,5-HAT-Enabled Boron Radical-Polar Crossover

Carboranes are an important class of boron cluster compounds with broad applications in medicine, materials science, and catalysis. However, the site-selective functionalization of their B–H bonds remains a long-standing challenge owing to the nearly identical chemical environments and high bond dissociation energies...

Li-Xin Li, Zi-Teng Yang, Shi-Chao Li et al. · 0 citations

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