Interfacial Cations Modulate CO2 Reduction Selectivity by Shaping Hydrogen-Bond Networks and Water Orientation
Electrochemical CO2 reduction (ECR) is highly sensitive to the electrode-electrolyte interfacial microenvironment (EEIM). However, how the hydration structures of alkali-metal cations reorganize EEIM and thereby influence the energetics of ECR and hydrogen evolution reaction (HER) related elementary steps remains unc...