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Sep 2026

Engineering a Hydrazone-Linked Covalent Organic Framework as a Cooperative Macromolecular Ligand for Recyclable Cu-Catalyzed Chan–Lam Coupling

The design of robust heterogeneous catalysts that rival the performance of homogeneous systems remains a fundamental challenge. Herein, we report a hydrazone-linked covalent organic framework (DHPy-COF) engineered as a cooperative macromolecular ligand with preorganized (O,N,O)-tridentate chelation sites for Cu(II) i...

Fei Li, Dao-Zhen Wang, Yu-Meng Liu et al. · 0 citations
Sep 2026

A 3D Ag18 Cluster-Based Metal-Organic Framework as a Heterogeneous Catalyst for CO2 Cycloaddition and Knoevenagel Condensation

The rational design of three-dimensional (3D) metal-organic frameworks (MOFs) based on high-nuclearity silver clusters with well-defined structures and multiple catalytic functions remains a significant pursuit in synthetic materials science. Herein, we constructed a new 3D silver-cluster-based MOF, formulated as [(C...

Shan-Shan Zhang, Jian-Ning Zhang, Shi-Ling Song et al. · 0 citations

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