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Yu-Chuan Xu

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Oct 2026

Decoupling Electronic Coupling and Site-Energy Asymmetry in a Scaffold-Free π-Assembly

In conventional π-stacked systems, electronic coupling (J) and site-energy asymmetry (Δε) are governed by the same structural coordinate. Co-facial packing maximizes J but enforces Δε ≈ 0, yielding symmetry-equivalent local-excitation-charge-transfer (LE-CT) manifolds near the charge-resonance/excimer limit, whereas...

Yi-Fei Wei, Jing-Jing Guo, Yu-Chuan Xu et al. · 0 citations

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