Covalent organic frameworks (COFs) represent a powerful class of ordered porous materials, yet conventional solvothermal synthetic routes often hinder their practical implementation. Solvent-free strategies have emerged as attractive alternatives, not only for reducing the use of conventional solvents but also for crea...
Qing-Yun Zhang, Kai-Yuan Wang, Dong Wang et al.· Angewandte Chemie· 0 citations
Aqueous Zn-ion batteries are promising due to their high safety, low cost, and environmental friendliness, but developing cathode materials with high capacity, excellent rate capability, and long cycle life remains challenging. Herein, we design and construct a series of highly crystalline, stable, and porous polyimide...
Yi Yang, Mengjin Wang, Jie Ma et al.· Journal of the American Chem...· 0 citations
Stacking isomerism in covalent organic frameworks (COFs) has long remained elusive, with no unambiguous single-crystal structure confirmation to date. Herein, we present the first definitive structural resolution of stacking isomers in one-dimensional COFs, enabled by a solvent-directed modulation strategy. Two distinc...