Non-Covalent Host-Guest Extraction of Methanol Enables Enhanced Syngas-to-Methanol Conversion Over Hybrid Oxide-Porous Framework Catalysis.
Product formation is commonly regarded as the endpoint of heterogeneous catalysis, yet the subsequent fate of products near active surfaces critically affects catalytic turnover. For syngas-to-methanol conversion over Cu/Zn/Al (CZA) catalysts, product retention and re-adsorption represent an underappreciated limitation...