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Author

Zhong-Yan Cao

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Oct 2026

Synthesis of Pyrroloquinazolinones via Base-Promoted Domino Reaction of 7-Vinylindoles with In Situ Formed Isocyanates from Dioxazolones.

Herein, we report a novel base-promoted domino reaction between 7-vinylindoles and dioxazolones, enabling the efficient one-pot synthesis of pyrroloquinazolinone scaffolds in moderate to excellent yields (up to 95%). This transition-metal-free protocol employs readily available dioxazolones as isocyanate precursors and...

Xiao-Quan Qiu, Yu Xin, Jing-Lei Wang et al. · 0 citations
Oct 2026

Stereodivergent Synthesis of C-Glycosides from Glycals by Ni-Catalyzed Cross-Hydrocarbonylation of Alkenes.

C-Glycosides always significantly improve the physicochemical properties and pharmacokinetic characteristics of the native O- and N-glycosides and are one of the most powerful strategies for carbohydrate-based drug discovery. However, direct access to C-glycosides with control of stereochemistry from readily available,...

Cheng-Tao Wang, Yun-Long Xia, Xing Wei et al. · 1 citation

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