Steric Control over the Assembly of Zirconium Metal–Organic Cages Using Zirconium Clusters with Bulky Capping Ligands
Zirconium metal–organic cages are an emerging class of highly tunable supramolecular materials that feature porous structures as well as relatively high thermal and chemical stability. Self-assembly of zirconium cages with ditopic organic linkers can result in the formation of porous tetrahedral or less porous lanter...