Geometry-Controlled Cooperativity at Binuclear Fe2-N6 Sites Enables Selective FeIV═OGeneration for Durable Fenton-Like Oxidation.
Single atom catalysts (SACs) are emerging as a promising platform for Fenton-like water purification; however, their practical deployment is often constrained by the trade-off between high intrinsic activity and long-term stability. Here, we construct an N-bridged binuclear architecture that pairs isolated Fe-N4 sites...