Geochemical Variations and Chemical Weathering History of Holocene Coastal Sediments in the Western Bohai Bay

Abstract

Geochemical proxies in coastal sediments are widely applied to reconstruct past climatic and environmental changes, yet their sensitivity to climate versus localized depositional processes remains debated in dynamic land–sea interfaces. Here, we present major, trace, and rare earth element (REE) data from two Holocene sediment cores (QX01 and QX02) from the western coast of Bohai Bay to decouple provenance, weathering, and hydrodynamic controls. Provenance-sensitive trace element ratios (La/Sc and Th/Sc) and REE fractionation patterns indicate exceptional source stability dominated by the Yellow River and adjacent cratonic catchments throughout the Holocene, eliminating provenance shifts as a confounding variable. Since ~8 ka, an overarching upward increase in raw chemical index of alteration (CIA), accompanied by increasing Al/Si ratios and grain sizes, broadly aligned with the warm and humid Holocene Climate Optimum. Crucially, a highly significant linear relationship between grain size, Al/Si and CIA (R2 > 0.78) demonstrates that raw CIA variations were decisively modulated by sea-level-driven hydrodynamic sorting during the Holocene transgression, which shifted the depositional setting from high-energy fluvial regimes to low-energy marine settings, preferentially trapping fine-grained, clay-hosted aluminosilicates with inherently high CIA values. During the late Holocene (~5 ka to present), stabilizing sea-level conditions shifted the raw records into an elevated plateau punctuated by high-frequency fluctuations and localized geochemical anomalies, reflecting a dynamic interface sensitive to episodic fluvial floods or tidal/storm reworking that periodically introduced coarser, quartz-rich detritus. The resulting sorting-corrected CIAC removes the transgressive clay-trapping artifact and reveals a broad, subdued weathering plateau between ~8 ka and 4 ka BP, consisting with previous Chinese Loess Plateau weathering intensity. These findings highlight that in dynamic marginal-marine sinks, raw silicate weathering indices reflect physical sorting overprints, and hydrodynamic detrending is essential to extract genuine continental paleoclimate signals.