Predicted High $n$-Type $zT$ and Ultralow Lattice Thermal Conductivity in A$_2$AgIrCl$_6$ (A = Cs, Rb)

Abstract

A useful thermoelectric device must impede heat flow without impeding charge transport. Here, we examine how closely cubic Cs$_2$AgIrCl$_6$ and Rb$_2$AgIrCl$_6$ approach this balance using first-principles calculations of structural stability, chemical bonding, elastic response, lattice dynamics, and scattering-resolved carrier transport. Both materials satisfy the cubic elastic-stability criteria, and neither harmonic phonon spectrum contains an imaginary mode. Replacing Cs with Rb mainly exerts chemical pressure: the lattice contracts by 1.34\% and the Ag--Cl and Ir--Cl bonds strengthen, whereas the band-edge topology changes little. HSE06 calculations including spin--orbit coupling yield direct X-point gaps of 1.597 and $1.637\,\mathrm{eV}$ for Cs$_2$AgIrCl$_6$ and Rb$_2$AgIrCl$_6$, respectively. The three symmetry-equivalent X valleys have light electron masses of $0.43$--$0.57\,m_0$, whereas the hole masses span $2.10$--$4.68\,m_0$. For Cs$_2$AgIrCl$_6$ and Rb$_2$AgIrCl$_6$, respectively, the modified Debye--Callaway model gives lattice thermal conductivities of 0.346 and $0.428\,\mathrm{W\,m^{-1}\,K^{-1}}$ at 300 K, decreasing to 0.118 and $0.150\,\mathrm{W\,m^{-1}\,K^{-1}}$ at 800 K. Treating acoustic-deformation-potential, ionized-impurity, and polar-optical-phonon scattering with AMSET gives peak $n$-type $zT$ values of 2.81 and 2.36 at 800 K near $6\times10^{19}\,\mathrm{cm^{-3}}$. This response arises from the convergence of light, valley-degenerate electrons, intermediate doping, and weak lattice heat transport rather than from a single exceptional coefficient. The predicted values are experimentally testable targets, contingent on retaining the cubic phases and controlled electron doping at elevated temperatures.