Polyolefin elastomers (POEs) produced by ethylene/α-olefin copolymerization are indispensable for high-end applications such as photovoltaic encapsulation, precision microelectronic protection, advanced foamed footwear, and automotive lightweight components. α-Diimine nickel catalysts that operate through a chain-walki...
Amide bonds are among the most ubiquitous linkages in pharmaceuticals, agrochemicals, polymers, and natural products. Despite their importance, conventional methods for forming these linkages often suffer from drawbacks such as low atom economy, harsh reaction conditions, and the generation of considerable waste. In re...
Abstract Metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) are types of flexible materials that consist of a metal node bonded together by organic ligands. Because of their exceptionally flexible architectures and porosity, they are useful for gas storage, catalysis, separation, drug delivery, and...
Polythioctic acid (PTA) and its derivatives carrying disulfide bonds within the polymer backbone have emerged as leading candidates for yielding degradable and recyclable polymers. However, their development has been impeded by the persistent trade-off between degradability and mechanical strength, as well as the lack...
This review provides a comprehensive overview of polymers bearing five-membered cyclic carbonate (5CC) moieties, highlighting their role in advancing CO2 utilization and their unique applications based on 5CC moieties. 5CC structures are highly promising due to their unique chemical properties and the fact that their s...
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