Aug 2026· Advanced Functional Materials· 0 citations· 226 references
Abstract
Electrochemical energy storage and conversion systems powered by renewables underpin the clean energy transition, yet sluggish oxygen evolution reaction (OER) severely limits energy efficiency, driving demand for efficient OER catalysts. Perovskites stand out for adjustable electronic structures and strong catalytic activity. High‐entropy perovskites (HEPs), with multiple principal lattice elements, gain stable phases from configurational entropy and favorable electronic states via multicomponent synergy, promising OER performance. However, their vast compositional range renders trial‐and‐error development ineffective, hindering structure–activity analysis and targeted catalyst design. Covering oxide and halide HEPs, this review summarizes advances in HEP OER catalysts over four aspects: synthetic routes, performance regulation, mechanistic analysis via computation, and AI‐driven rational design (covering material screening, descriptor mining, and activity prediction). Unlike prior reviews covering separate high‐entropy oxides, standard perovskites, or general AI catalysis, this work builds a closed logical loop for HEPs spanning synthesis, experiment, mechanism, and rational design. An outlook on AI‐assisted HEP electrocatalysis is offered to inform the development of advanced OER catalytic systems.
Solid oxide cells (SOCs) are high-temperature electrochemical platforms for efficient energy conversion and chemical production in both fuel-cell and electrolysis modes. Practical deployment remains constrained by fuel-electrode coking, limited transport, and sluggish kinetics at reduced temperatures, electrolyte insta...
Jun-Meng Jing, Hao-Ran Wang, Zi-Wei Zheng et al.· Advances in Materials· 0 citations
The oxygen evolution reaction (OER) is a kinetically demanding anodic process in water electrolysis and related electrochemical energy-conversion systems. Its multistep proton-coupled electron-transfer kinetics and catalyst degradation under strongly oxidizing conditions limit overall efficiency and durability. High-en...
Chang Shen, Xin-Yu Zhang, Ya-Nan Zhou et al.· Advances in Materials· 0 citations
Green hydrogen is a key energy vector for low-carbon transition, yet water electrolysis remains constrained by sluggish reaction kinetics and the high cost of noble-metal catalysts. High-entropy oxides (HEOs), which contain multiple metal cations, exhibit characteristic high-entropy, lattice-distortion, sluggish-diffus...
Jie Yu, Hong-Bo Liu· Nanoenergy Advances· 0 citations
Photocatalysis has emerged as a promising approach for solar energy conversion and environmental remediation. However, its practical implementation is still hindered by limited charge‐separation efficiency, slow surface reaction kinetics, and insufficient catalyst stability. High‐entropy alloys (HEAs), with their c...
Meng-Ting Zhang, Guo-Zhi Ma, Lin Wang et al.· Rare Metals· 2 citations
Strain engineering has emerged as an effective strategy for tailoring the electronic structure and catalytic behavior of materials at the atomic scale. For electrochemical water splitting, the sluggish kinetics of the hydrogen evolution reaction and oxygen evolution reaction are largely limited by scaling relationshi...
Hao-Yang Wang, Yan Shang, Zhong-Rui Mei et al.· Advanced Energy Materials· 0 citations
Thermochemical energy storage (TCES) based on reversible redox reactions of metal oxides has emerged as a promising solution for high‐temperature energy storage in next‐generation concentrating solar power (CSP) systems. Among the candidate materials, perovskite oxides (ABO
3‐
δ
) are particularly attractive...
Rahul R. Bhosale, George Thompson, M. Mahtabi· Energy Storage· 0 citations
We use cookies to run the site and, with your consent, for analytics and to show ads.
See our Cookie Policy.
