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ConspectusThiamine diphosphate (ThDP)-dependent enzymes are among nature's most elegant biocatalysts for C-C bond formation and cleavage, typically operating through a two-electron umpolung mechanism. Although a small subset of ThDP enzymes, such as pyruvate: ferredoxin oxidoreductase (PFOR), has been shown to proceed...
Biotransformation plays a crucial role in addressing global challenges related to resource utilization and energy sustainability. Natural processes, such as photosynthesis and microbial metabolism, transform external resources into functional compounds. However, these processes are often constrained by inefficiencies...
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